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If you use a Water Stone on Shaymin in X & Y, it will evolve into Sonic the Hedgehog. Sonic is a Rock / Steel type.
also, if you catch a Staryu, kill 100 Bug-type Pokémon with it, then evolve it into Starmie; Misty will appear and take you to her gym. If you beat her, she will marry you.
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Oh, and if you use a water stone on Misty, she evolves into Wailord.
