considering how you are doing the job of what politics are supposed to be doing, aka negotiating deals among one another literally 24/7. That would make you better at passing laws that are fair and both sides are satisfied with. Also considering how you will meet a ton of people who do that for a living so your odds of putting people who are actually good at negotiating increases tenfold. You know how to create jobs because you are a CEO so you know what will work best if you are a long time CEO like Trump. Money management is way better because thats a huge part of your company. Detecting frauds, corruption, scams for companies or people are easier to detect since you need to know how to do that as a CEO to avoid people taking YOUR money (remember the all company money is money owned by the CEOs that has been reinvested into the companies, so yes it is there money).
The only thing politics have CEOs beaten at is how to get re elected. Thats all what politics know how to do. most politicans on the national level are absolute blokes and don't know what they are doing.